Clearly the Ring caused some Gollum have you seen my precious toilet paper shirt kind of psychological condition in poor Smeagol, but I don’t have the kind of knowledge or background to determine if what he had was schizophrenia or not. The movies certainly gave him a bit of multiple personality disorder so Andy Sirkis could made his lobby for an Oscar (apparently failing only because the Academy was too bone-headed to recognize a motion-captured actor as an award-able actor. This disorder was not as strong in the books, and at the time he was guiding the hobbits his insanity was suppressed. He was acting fairly rationally, including making detailed and realistic plans for getting the Ring back. However, Frodo was clearly starting to let that “master” thing get to his head a little bit, and he almost managed to permanently subjugate Gollum he DID succeed for a little while.
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It is possible that it was Gollum have you seen my precious toilet paper shirt a good thing he didn’t, as this might have prompted Frodo to claim the Ring earlier to disastrous result! Gollum follows the Fellowship through Moria. Tolkien makes it sound like he needed help to find his way out and that is why. However, then he waits for a month until they leave Lothlorien. I dont know if he could sense the Ring, or just saw hobbits and followed them for that reason. But he followed Sam and Frodo then into the eastern Emyn Muil. And after that point, I think Frodo makes it clear that he has the Ring.